Angelina Jolie

Angelina Jolie took on the role of an evil fairy in the movie Maleficent, and she transformed into one of the scariest villains to appear on the big screen. Her sharp jawline alone is enough to scare us, which is why we had to put her on this list.

While Jolie has played lots of heroes in her time, there’s nothing better than Jolie switching to the dark side. Jolie has won an Academy Award and three Golden Globe Awards over the course of her career, and she has been named Hollywood’s highest-paid actress multiple times. No wonder she makes such a good villain!